O, Christmas Tree! Scientists from the Centre for Sustainable Chemical Technologies (CSCT) at the University of Bath have developed a renewable plastic from a chemical called pinene found in pine needles. The researchers see uses in a range of applications, including food packaging, plastic bags and even medical implants.

Pinene is the fragrant chemical from the terpene family that gives pine trees their distinctive “Christmas smell” and is a waste product from the paper industry. Terpenes are an abundant class of natural products - available in citrus, turpentine, and pine oils - and they can be easily turned into chemical feedstock using existing petrochemical technologies.
Biobased polyesters such as PLA (polylactic acid), are made from crops such as corn or sugar cane. As brittleness can be a problem with PLA , it is sometimes mixed with a rubbery polymer called caprolactone to make it more flexible. Caprolactone, however, is made from crude oil, which means the resulting plastic is not totally renewable. The researchers publishing their results in the journal Polymer Chemistry, used pinene as the raw material to make a new type of plastic that can be used in the place of caprolactone.

Helena Quilter, PhD student at the CSCT, explained: “We’re not talking about recycling old Christmas trees into plastics, but rather using a waste product from industry that would otherwise be thrown away, and turning it into something useful.

“So if we can make a plastic from sustainable sources, it could make a big difference to the environment.”

Professor Matthew Davidson, Director of the CSCT and Whorrod Professor of Sustainable Chemical Technologies, added: “This research is part of a wider project that looks at using bio-based chemicals like pinene as a sustainable starting material for making a range of useful products, in the place of petrochemicals. This reduces our reliance on fossil fuels and provides a renewable feedstock that has the potential to revolutionise the chemical industry.”

The project, funded by the Engineering and Physical Sciences Research Council (EPSRC), is also investigating using other terpenes, such as limonene from citrus fruit, as a substitute for petrochemicals to make a range of products from plastics to pharmaceuticals.
The research is still at the early stages - only a few grams have been made so far - but the scientists aim to scale up the process to produce larger quantities in the near future.


http://www.bath.ac.uk/research/news/2017/01/04/plastic-from-pine-trees